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Catalan numbers are a sequence of natural numbers that occurs in many interesting counting problems like following.
1) Count the number of expressions containing n pairs of parentheses which are correctly matched. For n = 3, possible expressions are ((())), ()(()), ()()(), (())(), (()()).
2) Count the number of possible Binary Search Trees with n keys (See this)
3) Count the number of full binary trees (A rooted binary tree is full if every vertex has either two children or no children) with n+1 leaves.